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Feature from Environmental Building News
November 1, 1994
Carpeting, Indoor Air Quality, and the EnvironmentCarpeting has become ubiquitous in North America, covering more floors in homes, businesses, and institutions than all other floorcoverings combined. We love it for its softness, dirt-hiding ability, acoustic muffling, and low cost. Recently, however, carpets have come under fire for their potential role in indoor air quality problems, and they’ve been questioned for their typically short service life. Carpets have come to have two strongly contrasting images in our culture: they represent the warmth and comfort of home, but also the worst of our fossil-fuel based, disposable society. Carpets have been gradually increasing their share of the floorcovering world for the last few decades. Once a luxury reserved for the very rich, carpets and rugs now cover 70% of the floors in the United States. In 1993 Americans purchased 5.5 square yards of carpet per person, or nearly 1.5 billion square yards total—enough to cover nearly 40% of Rhode Island. Between 1960 and 1993, carpet purchases grew by 654%, while the average cost of carpets in real dollars dropped dramatically. Cheap fossil fuels and mass production have made very inexpensive carpet possible. Our look at carpets addresses the indoor air quality (IAQ) concerns and also some broader environmental questions.Health ConcernsIn 1988 the installation of new carpeting at EPA headquarters in Washington, D.C. led to a rash of health problems and complaints from the staff. This incident became the first highly publicized case of what has been called “sick building syndrome.” Although the cause of the problem was never verified, speculation has focused on the adhesives used to install the carpet and on a chemical by-product known as 4-PC (4-phenylcyclohexene), which is released from the carpet’s backing material. Several years later, in 1992, Dr. Rosalind Anderson in Dedham, Massachusetts ran some tests exposing mice to air drawn from carpet samples that people suspected were making them sick. Much to everyone’s surprise, many of the samples caused severe neurotoxic reactions and even death. Moreover, it wasn't only new carpet she was testing. Some of the samples were up to twelve years old. The Anderson Lab findings led to a flurry of activity and concern about health problems from carpets, but even now—two years after their first reports—little more is known about carpet toxicity, and some have cast serious doubts on the validity of the findings. Air quality expert Hal Levin explains that Anderson Labs is a commercial testing laboratory and not a research facility, and their methodology is not scientifically valid. The test Anderson uses, ASTM-E981, or the mouse bioassay test, was developed to determine respiratory irritation, not toxicity. The carpet samples from which the test air was drawn were heated to abnormal temperatures, and the mice were exposed to concentrations inappropriate even for the irritation test, according to Levin. Finally, the air samples to which the mice were exposed were never tested for concentrations of pollutants, even after the mice died. EPA scientists, using their own equipment in Anderson’s laboratory, also found mice dying, according to Anthony Pollino, an aide to Congressman Bernard Sanders who witnessed the tests. Yet when the EPA researchers attempted to replicate the results in their own labs, making modifications to increase the scientific validity of the tests, their results were much less conclusive. Although there are no widely accepted explanations for Anderson’s results, much of the scientific community refuses to support her work. “ I regard her results with a high degree of skepticism,” says Dr. Alfred Hodgson of Lawrence Berkeley Laboratories (LBL). In a recent North Carolina court case concerning health effects of carpeting, the judge refused to admit Anderson’s affidavit testimony due to her lack of support from the scientific community.So What DO We Know?After receiving several hundred complaints about possible carpet-related health effects, the U.S. Consumer Product Safety Commission (CPSC) commissioned a study by Hodgson and others at LBL of chemical emissions from carpets. Dozens of chemicals released from carpets were observed and 31 were positively identified. Emission levels of these chemicals were then compared to existing data about their health effects. As the measured emissions were considered peak values to which people would be exposed for only a few hours or days, they were compared only to known short-term health effects. No attempt was made to assess the possible effect of chronic or long-term exposure. As measured, none of the chemicals approached levels known to be hazardous upon short-term exposure.
![]() New Carpet & Rug Institute consumer information label Adhesives & SealantsIt is not at all clear that the carpet itself is the biggest IAQ problem in new carpet installations. The carpet industry is quick to point out that carpet adhesives and seam sealants emit far more pollutants, especially in the first few weeks after installation. Carpet cushions, or pads, may be at fault as well. In a typical commercial installation, carpet adhesive is spread over the entire surface, covering between 7 and 16 square yards per gallon, depending on the carpet type. There are many different types of adhesives, but the majority are based on SB latex, the same resin used in carpet backing. With such a large volume used, adhesives have generally been by far the largest short-term source of VOC emissions, but change is underway. Although true solvent-based adhesives have not been used since 1970, most adhesives have continued, until recently, to use volatile solvents to emulsify, or liquefy, the bonding resin. Until 1990 VOC levels in these adhesives typically ranged from 200 to 600 grams per liter (g/l). Air quality regulations promulgated in 1990 in southern California limited VOCs in adhesives to 150 g/l. This became an accepted standard nationwide in 1991, according to Ken Knudtzon of DAP, chairman of the Floor Covering Adhesives Manufacturers Committee of the National Association of Floor Covering Distributors. The California regulations are based on VOC levels as calculated from the ingredients; actual levels measured in the adhesives tend to be slightly higher. Since 1991 IAQ concerns have led adhesive manufacturers to find ways to reduce solvent levels even further, and some now claim a calculated VOC level of zero. They have accomplished this reduction by using heat or other processes, instead of solvents, to emulsify the resin. Several manufacturers, including the W. F. Taylor Company and the Henry Company, now sell only low-VOC products, and products with calculated levels below 50 g/l are now available from all manufacturers. Early generations of low-VOC adhesives were harder to work with than traditional products, giving them a bad name with installers. “When the new adhesives first came out, their adhesion properties were not as good,” said Fred Williamson, president of the flooring firm CSI/CDC Corp. in New York City. Product performance is continually improving, however, as manufacturers get more experience with the new formulations. “We test some of our competitors’ products, and the ones they have now are better than the ones they had a year ago, which were better than the year before that,” Knudtzon reported. Although the low-VOC adhesives are at present more expensive to make, Knudtzon insists that the cost is no more than 5% higher to the installer. Seam sealants have been another serious offender, releasing known toxins including 1,1,1-trichloroethane and toluene. The trichloroethane must be eliminated by 1996 to meet new government regulations, and some manufacturers have introduced new formulations with zero calculated VOCs.Old Carpets May Be WorseMany IAQ experts suggest that the biggest problem with carpets may not be new carpet emissions at all. Once installed, a carpet acts like a filter for anything in the air, trapping particulates and pollutants. Anything carried onto a carpet on shoes or wheels can also become lodged in it. Hydrocarbons from a street or pesticides from a yard can enter the carpet matrix. Outdoors, ultraviolet sunlight eventually breaks down these chemicals, but in the carpet there is nothing to remove them. Frequent and effective vacuuming can reduce the accumulation of such contaminants, but not even hot-water extraction can eliminate them all. VOCs can be adsorbed onto carpet fibers, stored there for an indefinite time, and eventually released back into the air. Thus, carpet that is exposed when an area is painted, for example, can become loaded with VOCs from the curing paint. These VOCs can then add to the overall pollutant level in the space for an extended period of time, long after the paint has cured and stabilized. Wool fibers appear to have an even greater capacity than synthetics for trapping VOCs, especially formaldehyde and nitrogen oxides. Some wool-industry-sponsored research suggests that such substances are chemically bonded to the wool and will not be released, but such claims haven’t been verified. Carpets are also an ideal environment for dust mites, which consume flakes of dead human skin and leave highly allergenic excrement. Wet carpet is an ideal breeding ground for another allergen: mold and mildew. In fact, most experts recommend that any carpet that has been wet for over 24 hours be removed, because there is no effective way to eliminate the mildew growth. Some aggressive cleaning products can themselves leave toxic residues in carpet, especially if they are improperly used.Broader Environmental Issues
![]() Extrusion of nylon fibers
![]() Typical carpet construction SB LatexBacking materials such as styrene butadiene latex are highly reactive compounds, made up of several toxic components. Because they are applied at the carpet mill in liquid form, they may not always see ideal curing conditions. “The fibers themselves are very clean,” LBL’s Hodgson said. “Almost all of the emissions are originating from the backing materials.” 4-PC is an unwanted by-product of SB latex production that occurs when manufacturing conditions and mixtures are imperfect. Even though tests have failed to turn up any evidence of serious toxicity, the industry has reduced average 4-PC levels from 250 ppm to less than 90 ppm since the public concern about 4-PC surfaced in the late 1980s. Indoor Air Bulletin reports that some recent tests of SB latex have revealed non-detectable levels. Apparently public concern has led to better quality control. In some carpet products small amounts of SB latex are used to attach secondary backings of polypropylene or polyurethane. Woven carpets, because they are inherently more stable than tufted carpets, also require far less adhesive backing.PVC
![]() PVC-backed carpet tiles from Interface Flooring Systems, Inc. Carpet PadsFive types of carpet cushion are commonly used today: bonded urethane, prime urethane, sponge rubber, synthetic fiber, and rubberized jute. Bonded urethane, the most common cushion for residential installations, is made by bonding together scraps of urethane cushion material from the automotive and furniture industries, and from old carpet cushion. Prime urethane is made by foaming large “loaves” of urethane and then slicing them into sheets. While the foaming used to be done with ozone depleting CFCs, hydrocarbons such as methyl butane are now commonly used. Sponge rubber cushion is synthetic rubber material than has been vulcanized, or foamed. Off-spec or waste fibers from carpet manufacture are sometimes made into firm cushion for use where a spongy feel isn’t desirable. For all-natural carpet systems, jute fiber bonded with natural latex is available from specialty suppliers.Carpet DyeingCarpet dyeing has traditionally been one of the most polluting stages in the carpet manufacturing process, as large amounts of contaminated water are dumped from used dye-baths. Among dyeing systems, piece dyeing of carpets is generally the most wasteful method. Solution dyeing of nylon is the most environmentally responsible method. Pure pigments are added to the polymer solution as the fibers are extruded. Once a specialty item, solution-dyed nylon is becoming increasingly common, but it works best when making large runs of single-color carpet. Otherwise a lot of nylon can be wasted in trying to match colors on a production run, according to Jerry Dickerson of Monsanto’s research division. Some carpets are not dyed at all, but printed after assembly using textile printing techniques.Carpet TreatmentsCarpets and carpet fibers are treated in many different ways to achieve desired qualities. Among these, stain-resistant fiber treatments, such as Scotchguard™, have become standard in recent years. While industry representatives insist that such treatments are safe, some consumers are convinced otherwise. Antistatic and antimicrobial treatments are also used. Another process that has a history of environmental problems is the mothproofing of wool carpets. In Europe, where wool carpets are more common, contamination of waterways with insecticides has been a major issue. Most countries have strict regulations governing release of polluted water, so a lot of effort has gone into new approaches. Westex Carpets, in the U.K., is using one of the newest, called the Autofoam Mothproofing System. Along with environmental concerns, mothproofing chemicals in the carpet are also a health concern for many. Kirsten Childs of the Croxton Collaborative specified wool carpet for the Audubon headquarters remodel in New York City, and considers the mothproofing a necessary evil. For homes, some prefer untreated wool carpet, but this is hard to find.Reducing Waste in the IndustryMany mills are finding ways to improve their processes to save money and natural resources. After Ray Anderson, CEO of Interface, became committed to making his company a good environmental steward, many improvements became possible. At one plant in LaGrange, Georgia, for example, water use has been cut from 12 million gallons per month to less than 3 million. Technical Manager Lewis Engle reports that the savings were accomplished by finding ways to recycle water from one process to another before discarding it. Solid waste disposal is also a major issue. Tons of off-spec fiber and carpet scraps build up every year, leading to many waste reduction and material re-use initiatives. Carpet fiber is being tested as a reinforcement in concrete. Carpet manufacturer Shaw Industries, Inc., is building a new 120,000 ft2 research and development facility with used carpet fiber as reinforcement. Ten pounds of fiber per cubic yard of concrete was used for the floor slabs, driveways, and walls of the building. Another manufacturer, Collins & Aikman, is making plastic lumber profiles from whole used carpets. One of the most wasteful practices in the carpet industry is the use of large binders for distributing carpet samples to designers and architects. They are bulky, non-recyclable, and quickly become obsolete as new carpet styles are introduced. Interface Flooring Systems has addressed this problem by introducing new display binders made of recycled and recyclable corrugated cardboard. In another example of waste reduction, Hoechst Celanese recently changed the way they package bales of polyester fiber for shipment to carpet mills. Instead of wrapping the bales with polypropylene and metal straps, the entire package, including labels, is now polyester, like the fibers. It can all be returned to the company for recycling.RecyclingCarpet disposal is a major solid waste issue. Over 60% of the new carpet installed is replacing old carpet, amounting to about a billion square yards, or 3.5 billion pounds, of discarded carpet every year. With the tons of carpet piling up in landfills threatening to become another public relations problem for the industry, several carpet manufacturers and carpet fiber producers have been developing carpet recycling programs. Nylon is a relatively expensive polymer, so many companies are working on ways to separate the nylon face fibers from the carpet backing and recycle the nylon. One strategy is to chemically break down, or depolymerize, the nylon. Nylon 6, because it is based on a single source molecule, caprolactam, lends itself more easily to depolymerization than nylon 6,6. BASF and AlliedSignal, the two main suppliers of nylon 6 to the carpet industry, are both focusing on this strategy for remanufacturing virgin-quality nylon 6.
![]() Carpets collected by DuPont for recycling or incineration Recycled Content in CarpetsPET, or polyester, is the only carpet fiber made today with significant recycled content. Two hundred and seventy-three million pounds of polyester fibers are used in carpeting in the U.S., about half of which is recycled material. The most visible company producing carpet from recycled PET is Image Industries, Inc. (formerly Image Carpets). Image collects and processes post-consumer PET containers for recycling. Their in-house carpet manufacturing plant affords them an outlet for the lower spec and colored recycled resin that isn’t marketable for higher-grade uses. This outlet allows Image to specialize in recycling containers other than soda bottles. Non-soda containers tend to be more contaminated and harder to separate from other resins, making them undesirable to less sophisticated recyclers. Image also sells recycled PET resin to other carpet manufacturers, including Talisman Mills. Though not widely known in consumer circles, Wellman Inc. is an even larger recycler of PET resin, supplying several carpet mills. The recycled content of its material has been certified by Scientific Certification Systems, Inc., of Oakland, California. Polyester is generally considered to be a less durable fiber than nylon, so polyester carpets are usually used only in residential applications, which receive less wear than commercial installations. While carpet may be a good use for off-spec PET recyclate, high-quality recycled PET may be better reused in soda bottles or other fabrics where it can be recycled again. PET is not valuable enough to justify the cost of separating it from other fibers once it is in a carpet. PET recycler Wellman acknowledges that separating and recycling the PET from carpets is not currently economically feasible. Thus, PET carpets may be made of recycled material, but they are not yet recyclable. Another fiber manufacturer may soon increase the recyclability of PET carpets. Hoechst Celanese, the largest supplier of virgin polyester to the carpet industry, is developing a carpet system made entirely of polyester. Shaw Industries, the largest carpet manufacturer, is reportedly working with Hoechst to produce the carpet, named Treviera One. Four or five mills will be introducing the all-polyester carpets in 1995, according to Hoechst. Ironically, although the stated goal of producing the all-polyester carpet is easy recyclability, the product is not expected to be made with any recycled resin.Lifecycle AssessmentAs a fossil-fuel-based product, carpet is relatively energy intensive to produce. Most carpet is made using petrochemicals. Even if they are in a safe form in the final product, which some might question, these chemicals must be contained and handled very carefully during manufacturing to prevent environmental and health problems. But carpet’s biggest drawback from a lifecycle perspective is its short useful life compared to other floorcoverings. The most commonly quoted useful life for both residential and commercial carpet is eight years. Allowing for replacement costs, any long-term lifecycle cost or environmental lifecycle assessment paints a harsh picture of carpet. A recent study by Canada Mortgage and Housing Corporation comparing the embodied energy and environmental impacts of several flooring materials pronounced carpet to be the worst. Similarly, an environmental lifecycle assessment comparison of linoleum, vinyl, wool carpet, and nylon carpet from the University of Utrecht in The Netherlands put the nylon carpet at the bottom. Indoor air quality impacts of the materials were not considered in this Dutch study, which pronounced natural linoleum the clear winner, followed by wool carpet, sheet vinyl, and nylon carpet. The wool carpet compared in the study was tufted, with synthetic backing and adhesive, not natural backing. The energy required to ship the wool from New Zealand was estimated at 10% of the total embodied energy of the carpet and would likely have been an even higher fraction of the total for all-natural carpet. Both of these lifecycle assessments looked only at standard residential carpet products. These products typically use lower-quality nylon and relatively large amounts of SB latex adhesive—about 28 ounces per square yard of carpet—to bind the fibers to the backing. Some higher-quality commercial-grade carpets are likely to be less toxic and may rate better from an overall environmental perspective. Woven carpets, for example, require far less adhesive than the far more common tufted products. In spite of all the research and development that has gone into synthetic fibers for carpets, wool is still considered the most desirable fiber, according to CRI, and for good reasons. Wool has appearance characteristics that synthetics have not yet matched, it has natural flame resistance, and it remains more durable than most synthetics. In fact, after the World Trade Center bombing in New York last year, extensive repairs were done to the main lobby with the original wool carpet in place, on the assumption that it would have to be replaced. After the last machines drove out, however, the managers discovered, much to their surprise, that with a thorough cleaning the carpet remained as good as new.ConclusionA rash of alleged health problems with carpet have yet to be properly explained, suggesting that all carpets, and especially the less expensive synthetics, should be used with great caution. In addition, the relatively short life expectancy of most carpet and the heavy dependence on fossil fuels as a raw material make it incumbent on those specifying carpet to see that it will be maintained and protected for a long, safe service life. The recommendations that follow are far from exhaustive, but they are a step towards safer, better floorcoverings.For more information: Marilyn Black, Chief ScientistAir Quality Sciences, Inc. 1331 Capital Circle Atlanta, GA 30067 404/933-0638 Rosalind Anderson Anderson Laboratories Inc. 30 River Street Dedham, MA 02026-2948 617/364-7357 The Carpet and Rug Institute P.O. Box 2048 Dalton, GA 30722 706/278-3176, 706/278-8835 (fax) Hal Levin, Editor and Publisher Indoor Air Bulletin 2548 Empire Grade Santa Cruz, CA 95060 408/425-3946, 408/426-6522 (fax) Informed Consent P.O. Box 935 Williston, ND 58802-0935 701/774-7760 William H. Oler Executive Director Carpet Cushion Council P. O. Box 546 Riverside, CT 06878 203/637-1312 203/698-1022 (fax) Kenneth Knudtzon Chairman FCAMC c/o DAP, Inc. P. O. Box 277 Dayton, OH 45401 513/667-4461, x 2257 513/667-3840 (fax) Styrene Butadiene Latex Manufacturers Council, Inc. 655 15th Street, NW, Suite 1200 Washington, DC 20005 202/879-5202 202/638-2103 (fax) Todd Stevenson, Freedom of Information Officer Office of the Secretary US Consumer Product Safety Commission Washington, DC 20207 301/504-0785 301/504-0127 (fax) Sidebar: Mechanical Carpet FasteningMechanical Carpet FasteningTacFast™ is a hook-and-loop (“Velcro”) carpet fastening technology that is licensed on a royalty basis to carpet manufacturers. The principle is very simple: a fabric with protruding fiber loops is attached to the back of the carpet, and a four-inch-wide tape with hooks on the back goes down on the floor. The hook tape is installed around the perimeter of rooms, at all carpet seams, and any other place where extra bonding of the carpet is advised. Tape for the TacFast system is manufactured by both Velcro Industries and 3M. This system holds the carpet firmly in place, yet permits easy removal for repositioning or replacement. Wes Conneley, a technical manager for Wools of New Zealand, was sold on TacFast when he saw it working at the North York Performing Arts Center in Ontario, Canada. Painters working on a section of wall had simply peeled the carpet back out of harm’s way and were saved from the usual hassle of protecting a carpet from spills and splatters.For details, and a list of participating carpet mills, contact TacFast Systems Canada Limited, 15 Wertheim Court, Suite 102, Richmond Hill, ON L4B 3H7, Canada; 905/886-0785, 905/886-5765 (fax). Checklist: Checklist for Minimizing IAQ Problems With CarpetsChecklist for Minimizing IAQ Problems With CarpetsSpecifying Carpet• Consider alternatives: Many people prefer hard flooring with natural-fiber area rugs instead of wall-to-wall carpeting. Area rugs can be easily removed for cleaning when necessary, or to dry out if they get wet. This strategy avoids both new carpet emissions and old carpet problems like accumulated toxins and mildew. • Demand a warranty of safety: If your job is big enough to get manufacturers’ attention, you should require test results far more detailed than the industry’s label requirements. IAQ consultant Hal Levin suggests looking for total VOC emissions below 100 micrograms per square meter per hour, measured after 24 hours. Have the manufacturer specify the adhesive as well, and request a warranty of total VOC emissions for the installation. • Look to the CRI label as a minimum standard, but not as a guarantee of safe carpet. Companies not participating in the CRI program should be held to standards at least as strict. Be sure to consider carpet pads, adhesives, and seam sealants when evaluating emissions of a carpet system. • Keep carpet away from entrances where toxins tracked in from outside can collect, and away from water sources that might wet the carpet. Only use carpet if proper maintenance can be assured. • Avoid adhesives if possible. In homes and small commercial buildings specify only tackless strips at room perimeters. In commercial applications where heavy use or large spaces make perimeter connection insufficient, look for non-adhesive fastening systems such as Tac-Fast™, products that can be installed with double-stick tape, or peel-and- stick carpet tiles. • Specify low-VOC seam sealant.During Installation• Clean old carpet before removal. There is a tendency to neglect carpet maintenance in the period leading up to replacement, according to consultant Brian Greenberg of Toronto, Canada. That can be a big mistake because the carpet, which has been filtering and collecting dust and dirt of all types, will likely release much of it back into the space when it is torn up. Those particles circulating in the air and HVAC system can themselves cause an IAQ disaster. • Clean area thoroughly. Once the old carpet is removed, clean the entire space as thoroughly as possible to remove dirt and contaminants that may have been trapped under the carpet or newly released into the air from it. Removal of the old carpet is an important opportunity to get rid of everything trapped in and under it, and the opportunity is missed if the whole space isn’t cleaned before the new carpet is installed. • Pre-ventilate carpet elsewhere. All the chemicals known to offgas from new carpet drop off significantly after several hours to several days. By unrolling and airing out new carpet for several hours or days in an uninhabited, well-ventilated space, most of the chemical emissions from the carpet itself can be avoided. In practice this treatment is not feasible for most installations, but it’s a good idea when possible. • Avoid using conventional adhesives. If adhesive is needed, use only solvent-free, low-VOC products. These products can be more sensitive to ambient conditions such as temperature and humidity, so follow manufacturers’ directions carefully. • Maximize ventilation during installation. Pass as much air as possible through the space during installation and for several days or weeks afterwards. If possible, ventilate the area directly to the outside, bypassing any ductwork where VOCs could accumulate. Some consultants have suggested that heating the space with a new carpet to above-normal temperatures while increasing ventilation might cause more chemicals to offgas from the carpet, making it safer for occupants. So far there is no evidence that this method is more effective at reducing ambient pollutant levels than simple ventilation. • Isolate area from rest of building. If part of the building is being carpeted while the rest is occupied, it’s important to isolate the area being worked on and ventilate it directly to the outside. Definitely avoid circulating air from the newly carpeted area into other parts of the building. • Clean the new carpet. Have the installer thoroughly vacuum the new carpet with a high-efficiency particulate air (HEPA) filtration vacuum to remove any loose fibers or particles resulting from the installation process. • Vacate for as long as possible. Schedule any carpet installation to allow as much time as possible before the space is inhabited. In offices, just before long weekends is best if workers cannot be temporarily displaced on workdays. In homes, plan to be away for several days if possible after the installation, and keep bathroom or other exhaust ventilation fans running.General Maintenance• Clean often and thoroughly. Regular vacuuming is critical to controlling contaminant levels in carpets, but typical paper vacuum bags often recirculate more dust than they hold. HEPA-style filters are recommended for trapping particles as small as 0.3 microns. In homes, use the most efficient vacuum system available. For deep cleaning, consultant Brian Greenberg recommends hot water extraction performed by well-trained technicians. • Dispose of wet carpet. Carpet that has been saturated for over a day is likely to have mold and mildew contamination that is very difficult to control. Rather than risk breeding these allergens or exposing people to toxic treatments, most experts recommend simply replacing the wet carpet. • Ensure adequate, continuous ventilation. Minimum ventilation levels should be maintained to prevent any build-up of toxic emissions in the space. To be effective, ventilation must be well distributed throughout the space.IMAGE CREDITS: 1. (no credit) 2. 3. 4. (no credit) 5. (no credit) |
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