Blog Post

A Heat Pump Using Carbon Dioxide as the Refrigerant

A new generation of CO2-based heat pumps could avoid the high global warming potential of standard refrigerants and generate much higher temperatures

A Mayekawa Unimo air-to-water heat pump installation in Australia. Click to enlarge.Photo Credit: Mayekawa

In researching and writing about building products for Environmental Building News over the past twenty-plus years I’ve had an opportunity to cover some fascinating breakthrough products and technologies. One such technology I was writing about a few weeks ago is the use of carbon dioxide as a working fluid for heat pumps

But let me back up with a little context about refrigerants. These are the fluids used in refrigerators, air conditioners, and heat pumps that transfer heat from one place to another in cooling or heating a space. This “vapor-compression-cycle” equipment takes advantage of the principle that compressing a gas absorbs heat and expanding it releases heat—so it’s a way to move heat from one place to another.

When this compression and expansion cycle results in a phase change (converting it from liquid to gas or vice-versa), significant heat can be absorbed and released.

Problems with refrigerants

Over the past 35 years, refrigerants have come under fire—both for their impact on the Earth’s protective ozone layer and for their global warming potential (GWP). HCFC-22 (R-22), a hydrochlorofluorocarbon, has long been the most common refrigerant. But it is being phased out according to the international treaty to protect the Earth’s protective ozone layer.

That’s a good thing, as R-22 is both a significant ozone depleter and a significant greenhouse gas. The HFC (hydrofluorocarbon) refrigerants that have replaced HCFC-22 are much better from an ozone-depletion standpoint (ozone depletion potential or ODP of 0), but they are still very significant greenhouse gases (high GWP).


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An EcoCute water-to-water heat pump (next to the large tank) at the Somerston Winery in Napa Valley, California.Photo Credit: Mayekawa

Using CO2 as a refrigerant

These concerns with HCFC and HFC refrigerants have led to interest in other chemicals that can be used as refrigerants, one of which is carbon dioxide (CO2). The Japanese have focused considerable attention on CO2-based heat pumps, and one Japanese company, Mayekawa, has been selling commercial-scale CO2-based heat pumps in North America for several years.

Mayekawa offers three different CO2 heat pumps, the EcoCute water-to-water heat pump, the Unimo air-to-water heat pump and the Sirocco water-to-air heat pump. (The product name, EcoCute, got a little bungled in translation from the Japanese. “Eco” is short for “ecological” in the U.S., while ”cute” is derived from a Japanese kyūtō, meaning “supply hot water.”) The term “EcoCute” is used generically by a number of Japanese manufacturers.  

All three of the Mayekawa heat pumps have 25 kilowatt (kW) motors, so they are considerably larger than the heat pumps used for homes.

High efficiency is an important benefit of such systems; they operate at a coefficient of performance (COP) of about 4.0. If they are configured to provide space cooling in addition to hot water (just the water-to-water and air-to-water models), the COP can be as high as 8.0.

Higher output temperatures

From a performance standpoint, the big difference with CO2-based heat pumps is that they can produce much higher-temperature output. Exactly why they can do this is complex and has to do with CO2 being a “transcritical” refrigerant and doesn’t fully change phase like other refrigerants—described in detail in the article on Mayekawa heat pumps that I wrote for the August issue of Environmental Building News.

Detail of the EcoCute heat pump at the Somerston Winery, showing a large buffer tank.Photo Credit: Mayekawa

The EcoCute water-to-water heat pump and the Unimo air-to-water heat pump can produce water at up to 194°F—far hotter than that produced by standard heat pumps. This is significant, because it makes them viable for hydronic (baseboard hot-water) heating. As my friend and energy engineer Marc Rosenbaum, P.E. told me, if this can be done affordably, it will be a “game changer.”

One challenge with CO2-based heat pumps is that they need a fairly large lift temperature to operate. This is the difference in temperature in a heating loop between the supply and return temperature.

A standard gas- or oil-fired boiler may deliver 180°F water for hydronic heating, and return water in the heating loop at a temperature of 150°F after delivering it’s heat through baseboard radiators. So the boiler has to “lift” the water from 150°F to 180°F. That isn’t enough lift for a CO2-based heat pump. The EcoCute needs a minimum of about 45°F of lift to function effectively.

Higher pressure

The other challenge is that CO2 refrigerant cycles operate at far higher pressure than standard vapor-compression-cycle equipment. At the evaporator side the pressure can be about 600 pounds per square inch (psi), while in the gas cooler (which replaces the condenser in a standard compression-cycle device), the pressure can be 1,500 to 1,800 psi.

The higher pressure and the need for more robust (and more expensive) components to contain that pressure has slowed the development of CO2-based heat pumps.

An EcoCute installation in Quebec, Canada with multiple units.Photo Credit: Mayekawa

The future of CO2-based heat pumps

I gather that several manufacturers of popular mini-split heat pumps are developing residential-scaled CO2-based heat pumps and that those heat pumps are currently undergoing testing.

It will be fascinating to see what emerges. What excites me is that such heat pumps increase the potential of providing more of our energy needs using electricity generated by sunlight as an alternative to burning fossil fuels. There are challenges, certainly, but such products could help us transition to a solar future.

Alex is founder of BuildingGreen, Inc. and executive editor of Environmental Building News. In 2012 he founded the Resilient Design Institute. To keep up with Alex’s latest articles and musings, you can sign up for his Twitter feed.

Published August 28, 2013

(2013, August 28). A Heat Pump Using Carbon Dioxide as the Refrigerant. Retrieved from

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January 1, 2014 - 6:48 pm

This is almost like reading about the work of Jorn Stene at Sintef ten years back or so.

A coincidence?